61381-00-8Relevant academic research and scientific papers
A new palladium(II) complex of a functionalized N-heterocyclic carbene: Synthesis, characterization and application in Suzuki-Miyaura cross-coupling reactions
Linninger, Claudia S.,Herdtweck, Eberhardt,Hoffmann, Stephan D.,Herrmann, Wolfgang A.,Kühn, Fritz E.
, p. 192 - 197 (2008)
trans-[PdBr2(NHC)Im] was prepared by reacting the corresponding imidazolium (Im) salt with palladium(II) acetate in dimethylsulfoxide in an in-situ reaction without generating a free carbene. Both the salt and the complex were characterized spectroscopically and by X-ray structure analysis. The complex was tested in homogeneous Suzuki-Miyaura cross-coupling reactions.
Oligonucleotide analogs containing sulfur linkages
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, (2008/06/13)
Analogs of DNA containing sulfides, sulfoxides, and sulfones as linking groups between subunits capable of forming bonds with natural oligonucleotides are described. The analogs are lipophilic, stable to chemical degradation under a wide range of conditions and stable to enzymatic degradation in vivo.
