61389-12-6Relevant academic research and scientific papers
Exo- and endohormones XXI 1: Stereoselective synthesis of the four isomers of the 4,7-tridecadien-1-yl acetate. (4E,7Z)-4,7-tridecadien-1-yl acetate, the sex pheromone of the leafminer moth Phylonorycter corylifoliella
Ganscǎ, Lucia,Gocan, Alexandra,Oprean, Ioan,Maxim, Sanda,Budae, Iuliana
, p. 1243 - 1248 (2007/10/03)
The synthesis of the four isomers of 4,7-tridecadien-1-yl acetate, based on a C5+C8 scheme is described. The coupling reaction took place between the Grignard reagent of pent-4-yn-1-oic acid and 1-bromo-2(Z/E)-octene. The four isomers were separated on SiO2-AgNO3 TLC plate and GS-MS. (4E,7Z)-4,7-Tridecadien-1-yl acetate is the sex pheromone of the spottet tentiform leafminer moth Phylonorycter corylifoliella.
SYNTHETIC INVESTIGATIONS IN THE FIELD OF INSECT ATTRACTANTS (SEX ATTRACTANTS). II. SYNTHESIS OF FOUR ISOMERS OF 4,7-TRIDECADIENYL ACETATE AND (E,Z,Z)-4,7,10-TRIDECATRIENYL ACETATE
Ishchenko, R. I.,Kovalev, B. G.
, p. 258 - 262 (2007/10/02)
A common approach was developed to the synthesis of (E,Z)-4,7-tridecadienyl and (E,Z,Z)-4,7,10-tridecatrienyl acetates, which are the main components of the sex pheromone of the female potato moth Phtorimaea operculella, on the basis of 4-pentyn-1-ol and allyl halides.The Z,Z, Z,E, and E,E isomers of 4,7-tridecadienyl acetate were also obtained by the method.
