61434-25-1Relevant articles and documents
Formation of tertiary 3-nitro allylic alcohol by condensation of 2-chloroisobutyrophenone with nitromethanide anion: Estimation of Gibbs free enthalpies of reaction in solution for the reaction mechanism [1]
Ros, Francisco,Barbero, Inmaculada
, p. 1607 - 1617 (2005)
The reaction of 2-chloroisobutyrophenones and nitromethanide anion gives stereoselectively (E)-3-nitro allylic alcohols. The Gibbs free enthalpies of reaction in DMSO for carbanion addition, epoxide formation, and rearrangement to 3-nitro allylic alcohol,