61446-85-3Relevant academic research and scientific papers
Addition of trichloromethyl radicals to alkenes: The use of phosphites as hydrogen-atom donors in intermolecular radical reactions
Barks,Gilbert,Parsons,Upeandran
, p. 1719 - 1722 (2007/10/03)
Addition of trichloromethyl radicals (generated from BrCCl3 or CCl4) to a variety of alkenes in the presence of hydrogen-atom donors has been explored. The use of phosphites as hydrogen-atom donors was shown to provide a mild, novel and technically clean approach to trichloroalkanes.
Preparation of 1,1,1-trichloromethyl compounds
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, (2008/06/13)
1,1,1-Trichloromethyl compounds are prepared by a process in which chloroform is reacted with an olefin in the presence of a free-radical initiator and of a weakly basic alkali metal salt or alkaline earth metal salt, and are useful intermediates for the preparation of dyes, drugs and pesticides.
1,1,1-Trihalogeno-4-methylpentenes, method of preparing the same and use of the same in the preparation of 1,1-dihalogeno-4-methyl-1,3-pentadienes
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, (2008/06/13)
1,1,1-Trihalogeno-4-methyl pentenes and 1,1-dihalogeno-4-methyl-1,3-pentadienes are produced. These compounds are of value as intermediates for the production of pyrethrin analogs which are of use as insecticides or agricultural chemicals.
