61446-87-5

Usage

InChI:InChI=1/C6H9Cl3/c1-5(2)3-4-6(7,8)9/h3H,4H2,1-2H3

Upstream product

• 7647-01-0 hydrogenchloride 
• 17773-65-8 2-chloro-3-methyl-2-butene 
• 78-79-5 isoprene 
• 61446-85-3 1,1,1-Trichlor-4-methyl-4-pentanol 
• 556-82-1 3-methyl-2-buten-1-ol 
• 67-66-3 chloroform 
• 503-60-6 3,3-dimethyl-allyl chloride 
• 870-63-3 prenyl bromide 

Downstream Products

• 60066-84-4 ethyl 2,2-dimethyl-3-(2,2,2-trichloroethyl)-cyclopropanecarboxylate 
• 82095-83-8 (1R,3R)-3-(2,2-Dichloro-ethyl)-2,2-dimethyl-cyclopropanecarboxylic acid 2-isopropyl-5-methyl-cyclohexyl ester 
• 82095-83-8 (1R,3S)-3-(2,2-Dichloro-ethyl)-2,2-dimethyl-cyclopropanecarboxylic acid 2-isopropyl-5-methyl-cyclohexyl ester 
• 55667-43-1 1,1-dichloro-4-methyl-penta-1,3-diene 
• 61446-86-4 1,1,1-trichloro-4-methyl-4-pentene 

Relevant academic research and scientific papers

Synthesis method of 5,5,5-trichloro-2-methyl-2-pentene

The invention provides a synthetic method of 5,5,5-trichloro-2-methyl-2-pentene. The synthetic method comprises the following steps: taking 2-methyl-3-butene-2-ol as an initial compound of a reaction;adding a haloid acid into the reaction system, and conducting distilling to obtain an intermediate product 1-halo-3-methyl-2-butene; adding the intermediate product and chloroform into a reaction kettle, conducting stirring at a low temperature, and adding an inorganic base into the system in batches; wherein the reaction temperature is 0-40 DEG C, the reaction time is 2-10 hours, the mass ratioof the 2-methyl-3-butene-2-ol to the haloid acid in the reaction is (0.3-1):1, the weight ratio of the chloroform to the 1-halo-3-methyl-2-butene is (1-10):1, and the weight ratio of the inorganic base to the 1-halo-3-methyl-2-butene is (0.1-2.0):1. The method is high in reaction yield and low in environmental pollution degree, and the corrosion degree of equipment is reduced.

Process for the preparation of dienes

A process for the preparation of a diene of the formula STR1 in which X and Y are independently fluorine, chlorine or bromine Which comprises contacting a 1,1,1-trihalo-4-methyl-4-hydroxypentane of the formula STR2 in which X and Y have the previously assigned significance and Z is a chorine or bromine atom With a dehydrohalogenating agent and a dehydration agent.

1,1,1-Trihalogeno-4-methylpentenes, method of preparing the same and use of the same in the preparation of 1,1-dihalogeno-4-methyl-1,3-pentadienes

1,1,1-Trihalogeno-4-methyl pentenes and 1,1-dihalogeno-4-methyl-1,3-pentadienes are produced. These compounds are of value as intermediates for the production of pyrethrin analogs which are of use as insecticides or agricultural chemicals.