61511-54-4Relevant academic research and scientific papers
Efficient metal-free hydrosilylation of tertiary, secondary and primary amides to amines
Blondiaux, Enguerrand,Cantat, Thibault
, p. 9349 - 9352 (2014)
Hydrosilylation of secondary and tertiary amides to amines is described using catalytic amounts of B(C6F5)3. The organic catalyst enables the reduction of amides with cost-efficient, non-toxic and air stable PMHS and TMDS hydrosilanes. The methodology was successfully extended to the more challenging reduction of primary amides.
