615268-16-1Relevant articles and documents
Enantioselective cyclization of alkene radical cations
Crich, David,Shirai, Michio,Rumthao, Sochanchingwung
, p. 3767 - 3769 (2003)
(Matrix Presented) Enantiomerically enriched β-(diphenylphosphatoxy) nitroalkanes undergo radical ionic fragmentation, induced by tributyltin hydride and AIBN in benzene at reflux, to give alkene radical cations in contact radical ion pairs. These contact
Enantioselective alkene radical cations reactions
Crich, David,Shirai, Michio,Brebion, Franck,Rumthao, Sochanchingwung
, p. 6501 - 6518 (2007/10/03)
The reaction of enantiomerically enriched 2-methyl-2-nitro-3-(diphenylphosphatoxy)alkyl radicals with tributyltin hydride and AIBN in benzene at reflux results in the formation of alkene radical cation/anion pairs, which are trapped intramolecularly by am