615268-35-4Relevant academic research and scientific papers
Difunctionalization of ketones: Via gem -bis(boronates) to synthesize quaternary carbon with high selectivity
Zheng, Purui,Zhai, Yujie,Zhao, Xiaoming,Xu, Tao
supporting information, p. 13375 - 13378 (2018/12/13)
All-carbon quaternary centres are significant and prevalent structural frameworks but their preparation routes are rare and challenging, especially methods with common substrates. Herein, we report a convenient process to construct all-carbon quaternary c
Enantioselective alkene radical cations reactions
Crich, David,Shirai, Michio,Brebion, Franck,Rumthao, Sochanchingwung
, p. 6501 - 6518 (2007/10/03)
The reaction of enantiomerically enriched 2-methyl-2-nitro-3-(diphenylphosphatoxy)alkyl radicals with tributyltin hydride and AIBN in benzene at reflux results in the formation of alkene radical cation/anion pairs, which are trapped intramolecularly by am
Enantioselective cyclization of alkene radical cations
Crich, David,Shirai, Michio,Rumthao, Sochanchingwung
, p. 3767 - 3769 (2007/10/03)
(Matrix Presented) Enantiomerically enriched β-(diphenylphosphatoxy) nitroalkanes undergo radical ionic fragmentation, induced by tributyltin hydride and AIBN in benzene at reflux, to give alkene radical cations in contact radical ion pairs. These contact
