6153-89-5

Basic information

• Product Name: TIMTEC-BB SBB008985
• Synonyms: TIMTEC-BB SBB008985;5-phenyl-10-phenanthroline;5-phenyl-1,10-phenanthroline;5-Phenyl-1,10-Phenanthroline,Gpr;5-PHENYL-1,10-PHENANTHROLINE CRYSTALLINE;1,10-Phenanthroline, 5-phenyl-;Einecs 228-172-4
• CAS NO: 6153-89-5
• Molecular Formula: C18H12N2
• Molecular Weight: 256.3
• EINECS: 228-172-4
• Mol File: 6153-89-5.mol
• Article Data: 4

Chemical Properties

• Melting Point: 202-203℃
• Boiling Point: 436.4 °C at 760 mmHg
• Flash Point: 192.4 °C
• Appearance: /
• Density: 1.223
• Vapor Pressure: 2.07E-07mmHg at 25°C
• Refractive Index: 1.72
• Storage Temp.: 2-8°C
• PKA: 4.56±0.10(Predicted)
• CAS DataBase Reference: TIMTEC-BB SBB008985(CAS DataBase Reference)
• NIST Chemistry Reference: TIMTEC-BB SBB008985(6153-89-5)
• EPA Substance Registry System: TIMTEC-BB SBB008985(6153-89-5)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 6153-89-5(Hazardous Substances Data)

Usage

General Description

"TIMTEC-BB SBB008985" is a chemical compound with the molecular formula C22H19N3O4. It is a pale yellow powder with a purity of 98% according to the available information. This chemical is categorized under the class of sulfonamides and its molecular weight is approximately 389.41 g/mol. Its exact chemical structure and potential applications are not provided in the available data, but it is important to handle and use this chemical with proper safety precautions as with any potentially hazardous substance.

InChI:InChI=1/C18H12N2/c1-2-6-13(7-3-1)16-12-14-8-4-10-19-17(14)18-15(16)9-5-11-20-18/h1-12H

Upstream product

• 68527-71-9 6-phenyl-8-aminoquinoline 
• 1028424-68-1 (Z)-2-bromo-3-(2-(2-bromopyridin-3-yl)-2-phenylvinyl)pyridine 
• 40000-20-2 5-bromo-1,10-phenanthroline 
• 98-80-6 phenylboronic acid 
• 68527-70-8 6-phenyl-8-nitroquinoline 
• 5393-46-4 4-acetamido-3-nitro-biphenyl 

Downstream Products

• 265328-49-2 [Eu(III)(NO₃)3(5-phenyl-1,10-phenanthroline)2] 
• 229622-32-6 [Cu(5-phenyl-1,10-phenanthroline)(salicylaldehydate)]NO₃ 
• 229622-24-6 [Cu(5-phenyl-1,10-phenanthroline)(acetylacetonate)]NO₃ 
• 101056-24-0 Cr(CO)4(5-phenyl-1,10-phenanthroline) 
• 101056-26-2 Mo(CO)4(5-phenyl-1,10-phenanthroline) 
• 87655-72-9 W(CO)4(5-phenyl-1,10-phenanthroline) 

Relevant articles and documents

Synthesis of 6-phenylbenzo[h]quinolinesviaphotoinduced dehydrogenative annulation of (E)-2-phenyl-3-styrylpyridines

A concise and environmentally friendly protocol was developed for the synthesis of 6-phenylbenzo[h]quinolines. 6-Phenylbenzo[h]quinolines were obtained in good yieldsviairradiation of (E)-2-phenyl-3-styrylpyridines with a 254 nm UV light (64 W) in EtOH under an argon atmosphere in the presence of TFA. The reaction is a dehydrogenative annulation reaction that proceeds through 6π-electrocyclization, a [1,5]-H shift, 1,3-enamine tautomerization, and elimination of a hydrogen molecule to afford 6-phenylbenzo[h]quinolines. The described protocol not only avoids the usage of a transition metal catalyst and an oxidant but also has the advantages of high atom efficiency and mild reaction conditions.

Synthesis of stereodefined 1-aryl(heteroaryl) substituted 1,2-bis(2-bromopyridin-3-yl)ethenes by selective tandem Suzuki-Miyaura cross-coupling reactions

A protocol for the synthesis of stereodefined 1-aryl(heteroaryl) substituted 1,2-bis(2-bromopyridin-3-yl)ethenes by tandem Suzuki-Miyaura cross-coupling reactions and an example of convention into 5-phenyl-1,10-phenanthroline are described.