61540-43-0Relevant articles and documents
A New Synthetic Route to Aliphatic and Alicyclic Nitriles via Homolytic Desulfurization of α-(Dithiocarbamoylthio) Nitriles
Yanagawa, Makato,Moriya, Osamu,Watanabe, Yoshihiko,Ueno, Yoshio,Endo, Takeshi
, p. 2203 - 2204 (2007/10/02)
Chloroacetonitrile was transformed into aliphatic and alicyclic nitriles through (dimethyldithiocarmoylthio)acetonitrile.The key steps in the synthetic route consisted of mono- and dialkylation via sulfur-stabilized carbanion and homolytic desulfurization using tributyltin hydride.