615562-57-7Relevant academic research and scientific papers
A mechanistic dichotomy in ruthenium-catalyzed propargyl alcohol reactivity: A novel hydrative diyne cyclization
Trost, Barry M.,Rudd, Michael T.
, p. 11516 - 11517 (2003)
The cycloisomerization of diyne-ols catalyzed by [CpRu(CH3CN)3]PF6 to 2-vinyl-1-acylcycloalkenes proceeds via a ruthenacyclopentadiene involving initial ionization of the tertiary or secondary alcohol, followed by readditi
