615564-31-3Relevant academic research and scientific papers
Stereoselective Synthesis of 1,1′-Disaccharides by Organoboron Catalysis
Izumi, Sanae,Kobayashi, Yusuke,Takemoto, Yoshiji
supporting information, p. 14054 - 14059 (2020/06/10)
The highly stereoselective synthesis of 1,1′-disaccharides was achieved by using 1,2-dihydroxyglycosyl acceptors and glycosyl donors in the presence of a tricyclic borinic acid catalyst. In this reaction, the complexation of the diols and the catalyst is
Formation of 1,1-α, α-glycosidic bonds by intramolecular aglycone delivery. A convergent synthesis of trehalose
Pratt, Matthew R.,Leigh, Clifton D.,Bertozzi, Carolyn R.
, p. 3185 - 3188 (2007/10/03)
(Matrix presented) We report a new synthesis of trehalose analogs that involves the use of intramolecular aglycone delivery for stereoselective formation of the 1,1-α,α-glycosidic bond. The glycosylation reaction afforded the desired isomer exclusively and in good yield.
