615577-63-4

Upstream product

• 615577-58-7 Benzoic acid (1R,3R,4aR,5R,8aS)-4a-hydroxy-3-isopropenyl-5,8a-dimethyl-1,2,3,4,4a,5,8,8a-octahydro-naphthalen-1-yl ester 
• 615577-52-1 (2S,3R,5R)-2-allyl-3-hydroxy-5-isopropenyl-2-methylcyclohexan-1-one 
• 98-88-4 benzoyl chloride 
• 615577-61-2 Benzoic acid (1aR,2R,4R,4aS,8R,8aS)-2-(1-hydroxy-1-methyl-ethyl)-4a,8-dimethyl-2,3,4,4a,5,8-hexahydro-1aH-1-oxa-cyclopropa[d]naphthalen-4-yl ester 
• 615577-55-4 (1R,2S,3R,5R)-2-allyl-5-isopropenyl-2-methyl-1-[(1R)-1-methyl-2-propenyl] cyclohexane-1,3-diol 
• 615577-66-7 (3S,4aR,5R,8aR)-4a-hydroxy-3-isopropenyl-5,8a-dimethyl-1,2,3,4,4a,5,8,8a-octahydro-1-naphthalenone 
• 615577-60-1 Benzoic acid (1R,3R,5R,8aR)-3-(1-hydroxy-1-methyl-ethyl)-5,8a-dimethyl-1,2,3,5,8,8a-hexahydro-naphthalen-1-yl ester 
• 615577-59-8 Benzoic acid (1R,3R,5R,8aR)-3-isopropenyl-5,8a-dimethyl-1,2,3,5,8,8a-hexahydro-naphthalen-1-yl ester 
• 615577-57-6 (1R,3R,4aR,5R,8aS)-3-isopropenyl-5,8a-dimethyl-1,2,3,4,4a,5,8,8a-octahydro-1,4a-naphthalenediol 

Relevant academic research and scientific papers

A general, ring closure metathesis based enantiospecific approach to polyfunctional eudesmane, eremophilane and agarofuran sesquiterpenoids

An enantiospecific and stereo- and functional group diversity oriented approach to eudesmane, eremophilane and agarofuran sesquiterpenoids from (-)-carvone has been devised. RCM has been employed as the key reaction to generate the highly functionalized eudesmane framework. Further elaboration of the eudesmane framework to agarofurans and biogenetic-type rearrangement to eremophilanes is outlined.