61589-68-2Relevant articles and documents
MECHANISMS OF FREE-RADICAL REACTIONS. XIV. SELECTIVITY OF FREE-RADICAL CHLORINATION OF VALERIC ACID DERIVATIVES WITH ARYLCHLOROIODONIUM CHLORIDES
Dneprovskii, A. S.,Krainyuchenko, I. V.
, p. 324 - 328 (2007/10/02)
The free-radical chlorination of C4H9Y compounds with arylchloroiodonium chlorides was investigated.The reaction of the secondary C-H bonds increases as they become further from the electronegative substituent.The reaction parameters were calculated from the ratio of the β- and γ-monochlorides by means of the Taft equation.The absolute value of ρ increases with the introduction of electronwithdrawing substituents into the arylchloroiodonium chloride molecule.