61597-97-5Relevant academic research and scientific papers
Chiral N,N′-dioxide-FeCl3 complex-catalyzed asymmetric intramolecular Cannizzaro reaction
Wu, Wangbin,Liu, Xiaohua,Zhang, Yuheng,Ji, Jie,Huang, Tianyu,Lin, Lili,Feng, Xiaoming
supporting information, p. 11646 - 11649 (2015/07/15)
An environmentally benign catalyst, the N,N′-dioxide-FeCl3 complex, has been developed for the asymmetric intramolecular Cannizzaro reaction. Aryl and alkyl glyoxal monohydrates were applied to obtain α-hydroxy acid esters with excellent results. Deuterium-label and control experiments shed light on the reaction mechanism.
Study of enantioselective hydrogenation of bulky esters of phenylglyoxylic acid on Pt-CD and Pt-β-ICN chiral catalysts: Steric effect of ester groups and inversion of enantioselectivity
Szori, Kornél,Balázsik, Katalin,Felf?ldi, Károly,Bartók, Mihály
, p. 149 - 154 (2007/10/03)
Enantioselective hydrogenation of seven different esters of phenylglyoxylic acid was investigated by variation of the bulkiness at ester side of the substrates [Ph{single bond}C(O){single bond}C(O)OR, R = Me (l), cyclohexyl (2), adamantyl (3), cis-decahyd
