61616-94-2Relevant academic research and scientific papers
The cis- and trans-Effects of Cyanide in Substitution at Platinum(II)
Cattalini, Lucio,Guidi, Francesca,Tobe, Martin L.
, p. 233 - 236 (2007/10/02)
The cis- and trans- isomers (am = dimethylamine, pyridine, 4-cyanopyridine, 4-chloropyridine, 2-methylpyridine, 4-methylpyridine, 2,4-dimethylpyridine, 4-ethylpyridine, morpholine or piperidine), react rapidly with excess CN(1-) in methanol to
Nucleophilic displacement of the chelating bis(sulfoxide) from cis-[meso-1,2-bis(phenylsulfinyl)ethane]dichloroplatinum(II) and cis-[rac-1,2-bis(phenylsulfinyl)ethane]dichloroplatinum(II)
Cattalini, Lucio,Marangoni, Giampaolo,Michelon, Gianni,Paolucci, Gino,Tobe, Martin L.
, p. 71 - 75 (2008/10/08)
The kinetics of ring opening, by amines in 1,2-dimethoxyethane, have been measured for two bis(sulfoxide)-platinum(II) isomers. The results make possible a discussion of the differences between the two isomers, in comparison with other platinum(II) complexes, in terms of absolute reactivity, nucleophilic discrimination, and steric retardation effects.
