616238-32-5

Upstream product

• 116-11-0 2-Methoxypropene 
• 616238-31-4 triphenylmethyl 1-thio-α-D-mannopyranoside 
• 3695-77-0 triphenylmethanethiol 
• 4163-65-9 per-O-acetyl-α-D-mannopyranose 
• 857892-43-4 triphenylmethyl 2,3,4,6-tetra-O-acetyl-1-thio-α-D-mannopyranoside 

Downstream Products

• 616238-33-6 (4aR,6R,7S,8R,8aR)-8-Benzyloxy-2,2-dimethyl-6-tritylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 616238-34-7 Methanesulfonic acid (4aR,6R,7S,8S,8aR)-8-benzyloxy-2,2-dimethyl-6-tritylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 

Relevant academic research and scientific papers

A general method for the synthesis of sugar 2-C-sulfonic acids by 1 → 2 arylthio group migration in acid-sensitive thioglycosides. Direct transformation of thiotrityl ethers into C-sulfonic acids

(Matrix presented) Fully protected triphenylmethyl 2-O-mesyl-1-thio-β- D-gluco- (14) and -α-D-mannopyranoside (28) were transformed by a stereoselective intramolecular 1 → 2 trans-arylthio migration into methyl 2-S-triphenylmethyl-α-D-manno- (15) and -β-D