6165-54-4Relevant academic research and scientific papers
The Mechanism of Catalysis of the Thio-Claisen Rearrangement
Kwart, H.,Miles, W. H.,Horgan, A. G.,Kwart, L. D.
, p. 1757 - 1760 (1981)
The cyclization-induced rearrangement mechanism proposed by Overman to account for nucleophilc catalysis of the thio-Claisen rearrangement has been tested by application of two criteria, viz., the secondary kinetic deuterium isotope effect at the β (side
Catalyst free annulative thioboration of unfunctionalized olefins
Yang, Zhantao,Yang, Chun-Hua,Chen, Shiqi,Chen, Xixi,Zhang, Litian,Ren, Huijun
supporting information, p. 12092 - 12095 (2017/11/14)
A direct and catalyst-free annulative thioboration of unfunctionalized olefins has been developed. In the presence of BCl3 as the sole boron source, the boryl group and thiol group are added to the C-C double bonds simultaneously. The boronic acids obtained can be protected to form synthetically ubiquitous pinacol boronate esters.
