61653-34-7

Basic information

• Product Name: Diazene, bis(2-ethylphenyl)-
• CAS NO: 61653-34-7
• Molecular Formula: C16H18N2
• Molecular Weight: 238.332
• Mol File: 61653-34-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Diazene, bis(2-ethylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Diazene, bis(2-ethylphenyl)-(61653-34-7)
• EPA Substance Registry System: Diazene, bis(2-ethylphenyl)-(61653-34-7)

Safety Data

• Hazardous Substances Data: 61653-34-7(Hazardous Substances Data)

Upstream product

• 35774-47-1 1-azido-2-ethylbenzene 
• 35774-48-2 1-azido-2-(propan-2-yl)benzene 
• 14213-00-4 2,4,6-trimethylaniline azide 
• 612-22-6 2-nitro(ethylbenzene) 
• 98-95-3 nitrobenzene 
• 578-54-1 ortho-ethylaniline 
• 98306-73-1 N,N'-bis-(2-ethyl-phenyl)-hydrazine 

Downstream Products

• 578-54-1 ortho-ethylaniline 
• 76787-87-6 3,3'-diethyl-benzidine 
• 691-24-7 1,3-di-tert-butylcarbodiimide 

Relevant articles and documents

Azo synthesis meets molecular iodine catalysis

A metal-free synthetic protocol for azo compound formation by the direct oxidation of hydrazine HN-NH bonds to azo group functionality catalyzed by molecular iodine is disclosed. The strengths of this reactivity include rapid reaction times, low catalyst loadings, use of ambient dioxygen as a stoichiometric oxidant, and ease of experimental set-up and azo product isolation. Mechanistic studies and density functional theory computations offering insight into this reactivity, as well as the events leading to azo group formation are presented. Collectively, this study expands the potential of main-group element iodine as an inexpensive catalyst, while delivering a useful transformation for forming azo compounds.

Catalytic Nitrene Homocoupling by an Iron(II) Bis(alkoxide) Complex: Bulking Up the Alkoxide Enables a Wider Range of Substrates and Provides Insight into the Reaction Mechanism

The reaction of HOR′ (OR′ = di-t-butyl-(3,5-diphenylphenyl)methoxide) with an iron(II) amide precursor forms the iron(II) bis(alkoxide) complex Fe(OR′)2(THF)2 (2). 2 (5-10 mol %) serves as a catalyst for the conversion of aryl azides

POLYMER SUPPORTED REAGENTS AND METHODS OR REDUCING AROMATIC NITRO COMPOUNDS BY USING THE SAME

The present invention relates to a polymer supported reagent comprising a novel crosslinked mesoporous polymer, enabling a simple and easy production of an azoxy compound or an azo compound from an aromatic nitro compound, and a method of selectively reducing an aromatic nitro compound by using the same. The polymer supported reagent comprises a certain acrylamide mesoporous crosslinked polymer.