61666-77-1

Basic information

• Product Name: 1,3-Benzodithiole, 2-cyclohexyl-
• CAS NO: 61666-77-1
• Molecular Formula: C13H16S2
• Molecular Weight: 236.402
• Mol File: 61666-77-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,3-Benzodithiole, 2-cyclohexyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Benzodithiole, 2-cyclohexyl-(61666-77-1)
• EPA Substance Registry System: 1,3-Benzodithiole, 2-cyclohexyl-(61666-77-1)

Safety Data

• Hazardous Substances Data: 61666-77-1(Hazardous Substances Data)

Upstream product

• 108-85-0 1-bromocyclohexane 
• 55315-56-5 2-(3-methylbutoxy)-1,3-benzodithiole 
• 131549-15-0 2-<2-(2-methoxyethoxy)ethoxy>-1,3-benzodithiole 
• 931-50-0 cyclohexylmagnesium bromide 
• 118-92-3 anthranilic acid 

Downstream Products

• 2043-61-0 cyclohexanecarbaldehyde 

Relevant articles and documents

Enhanced Reactivity of Chelating Ortho Esters and Dithio-Ortho Esters Towards Grignard Reagents

2-Alkoxy-1,3-dithianes, 2-alkoxy-1,3-benzdithioles and bis(2-alkoxy-1,3-dioxolanes) react substantially faster with phenylmagnesium bromide and phenylethynylmagnesium bromide when the 2-alkoxy group can act as a chelating system for magnesium(II).

Oxidations with Lead Tetraacetate. IV. Oxidations of 1,3-Benzodithioles

Oxidations of 2,2-dialkyl and spiro with lead tetraacetate gave mainly sulfoxides and disulfoxides.The stereochemistry of these products was elucidated by n.m.r. spectroscopy.Oxidation of 2-methyl-2-aryl derivatives gave sulfoxides as minor products; here the main products were derived from attack on the methyl group forming acetoxy, diacetoxy, formyl and carboxylic acid derivatives and ring cleavage products. 2,2-Diaryl derivatives also formed small amounts of sulfoxides but ring cleavage products were predominant.Monosubstituted benzodithioles were very reactive and produced a variety of oxidation products, mostly unidentified.