61685-29-8

Basic information

• Product Name: Benzenemethanol, a-(1-methyleneheptyl)-
• CAS NO: 61685-29-8
• Molecular Formula: C15H22O
• Molecular Weight: 218.339
• Mol File: 61685-29-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(1-methyleneheptyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(1-methyleneheptyl)-(61685-29-8)
• EPA Substance Registry System: Benzenemethanol, a-(1-methyleneheptyl)-(61685-29-8)

Safety Data

• Hazardous Substances Data: 61685-29-8(Hazardous Substances Data)

Upstream product

• 63883-62-5 octan-2-one 2,4,6-tri-isopropylbenzenesulphonylhydrazone 
• 100-52-7 benzaldehyde 
• 111-13-7 hexyl-methyl-ketone 
• 98747-02-5 oct-1-en-2-yl trifluoromethanesulfonate 
• 617-86-7 triethylsilane 
• 629-05-0 n-octyne 

Downstream Products

• 1210492-31-1 (E)-2-methyl-1-phenyloct-2-en-1-ol 
• 49826-80-4 4-(2,2-dimethyl-3-phenylpropyl)-1-fluorobenzene 
• 108229-10-3 2-methyl-1-phenyl-1-octanol 

Relevant articles and documents

Platinum-catalyzed one-pot alkenylation of aldehydes using alkynes and triethylsilane: Dual catalysis by platinum(II) chloride

The PtCl2-catalyzed hydrosilylation of terminal alkynes with triethylsilane and subsequent alkenylation of aldehydes with the resultant (E)-alkenylsilanes in a one-pot manner are described. By adding p-benzoquinone and LiI, the latter alkenylation step proceeds smoothly to give allyl silyl ethers in moderate to high yields. This one-pot alkenylation is tolerant to a reasonable range of functional groups. PtCl2 plays a dual role as hydrosilylation and alkenylation catalysts.