616882-70-3

Upstream product

• 75-15-0 carbon disulfide 
• 110480-87-0 (R)-1-amino-2-methyl-1-phenyl-propan-2-ol 

Downstream Products

• 545443-69-4 (R)-2-(4'-bromobut-2'-enylthio)-4-phenyl-5,5-dimethyl-Δ²-1,3-oxazoline 
• 1258208-99-9 3-[(S)-2-methyl-1-phenylallyl]-5-p-methoxyphenyl-thiazolidine-2,4-dione 
• 1258208-96-6 3-[(S)-2-methyl-1-phenylallyl]-5-phenylthiazolidine-2,4-dione 
• 1263818-10-5 C₁₉H₁₈ClNO₂S 
• 1206518-13-9 (S)-3-(2-methyl-1-phenylallyl)-1,3-thiazinane-2,4-dione 
• 1206518-17-3 3-[((S)-2-methyl-1-phenylallyl)]-5-methylthiazolidine-2,4-di-one 

Relevant academic research and scientific papers

Rearrangement of oxazolidinethiones to thiazolidinediones or thiazinanediones and their application for the synthesis of chiral allylic ureas and α-methyl-β-amino acids

A novel rearrangement has been found between oxazolidinethiones and acyl halides under N-acylation reaction conditions to afford N-substituted 2,4-thiazolidinediones and N-substituted 1,3-thiazinane-2,4-diones. These heterocycles were used for the synthesis of chiral allylic ureas and α-methyl-β-amino acids.

A study of the alkylation and rearrangement products of chiral 1,3-oxazolidine- and thiazolidine-2-thiones

Homochiral 1,3-oxazolidine-2-thiones and 1,3-thiazolidine-2-thiones are useful chiral auxiliaries in asymmetric synthesis. Our interest in chiral amino dienes drove us to consider the preparation of dienes (1a) and (1b) bearing those auxiliaries. Trying t