61692-92-0Relevant academic research and scientific papers
Aluminum-Catalyzed Cross-Coupling of Silylalkynes with Aliphatic C-F Bonds
Jaiswal, Amit K.,Goh, Kelvin K. K.,Sung, Simon,Young, Rowan D.
supporting information, p. 1934 - 1937 (2017/04/11)
We report the generation of aliphatic and benzylic acetylenes via reaction of primary, secondary, and tertiary aliphatic fluorides with various trimethylsilyl acetylides. These reactions are catalyzed by Al and B Lewis acids, most effectively by the extre
Catalytic synthesis of allenes via isomerization of alkynes under phase- transfer catalyzed conditions
Oku, Makoto,Arai, Shigeru,Katayama, Kimiko,Shioiri, Takayuki
, p. 493 - 494 (2007/10/03)
Catalytic isomerization of alkynes to allenes under phase-transfer catalyzed conditions is described. Commercially available quaternary ammonium salt such as tetrahexylammonium bromide acts as a very effective promoter to accelerate the reaction under mil
