61727-66-0 Usage
Uses
Used in Organic Synthesis:
Acetyl azide, chlorois used as a derivatization reagent for the analysis of organic compounds. It aids in the identification and characterization of various organic molecules, enhancing the understanding of their structures and properties.
Used in Pharmaceutical Industry:
Acetyl azide, chlorois used as a key intermediate in the preparation of various pharmaceuticals. Its reactive nature allows for the synthesis of a wide range of drug molecules, contributing to the development of new treatments and therapies.
Used in Agrochemical Industry:
Acetyl azide, chlorois used in the synthesis of agrochemicals, such as pesticides and herbicides. Its application in this industry helps in the development of effective solutions for crop protection and management.
Used in Chemical Research:
Acetyl azide, chlorois utilized as a research tool in chemical laboratories. Its unique properties and reactivity make it an essential component in various experimental procedures, aiding in the advancement of chemical knowledge and innovation.
Check Digit Verification of cas no
The CAS Registry Mumber 61727-66-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,1,7,2 and 7 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 61727-66:
(7*6)+(6*1)+(5*7)+(4*2)+(3*7)+(2*6)+(1*6)=130
130 % 10 = 0
So 61727-66-0 is a valid CAS Registry Number.
61727-66-0Relevant academic research and scientific papers
A PARTICULARLY CONVENIENT ONE-POT SYNTHESIS OF N-ALKOXYCARBONYL, N-ACYL AND N-AROYL SUBSTITUTED IMINOPHOSPHORANES; IMPROVED PREPARATION OF AZIDOFORMATES, AROYL AND ALKANOYL AZIDES; AN ALTERNATIVE ROUTE TO COMPLEX AMIDES
Froeyen, Paul
, p. 161 - 172 (2007/10/02)
Chloroformates and acid chlorides react smoothly with sodium azide in acetone at 0 deg C, forming azidoformates, aroyl and alkanoyl azides in very high yield.With triphenylphosphine or other phosphines present in the reaction mixture, the forming azides are intercepted, leading directly to the corresponding N-alkanoyl, N-aroyl, N-alkoxycarbonyl, and N-aryloxycarbonyliminophosphoranes.N-acyliminophosphoranes react with n-butyllithium forming anions which react readily with electrophiles, e.g., carbonyl compounds, forming highly substituted iminophosphoranes.The phosphonium group is effortlessly removed from the latter compounds by acid hydrolysis forming the corresponding amides in high yield.Key words: Synthesis; iminophosphoranes; aroyl azides; alkanoyl azides; complex amides.
Kinetics of the Decomposition of Aliphatic Acyl Azides
Zlobin, V. A.,Tarasov, A. K.
, p. 140 - 141 (2007/10/02)
The kinetics of the decomposition of a series of aliphatic acyl azides have been investigated.The first-order rate constants and activation parameters have been determined and the influence of the substituents and of solvent polarity on the rate of decomposition has been established.
