61775-61-9Relevant academic research and scientific papers
Cross-aldol reaction between benzaldehyde and β-phenyiselanyl enoxysilanes derived from phenyiselanylmethylketones
Ponthieux, Sylvain,Outurquin, Francis,Paulmier, Claude
, p. 4017 - 4020 (1998)
The BF3-mediated aldol reaction between benzaldehyde and β- phenyselanyl enoxysilanes I derived from α-phenylselanylmethylketones has led to syn aldols 2 and α,α-bis(phenylselarryl) ketones 3 as by-products. Using tetrabutylammonium fluoride, the syn and anti aldols 2a were formed from 1a. Syn, syn-2-phenylselanyl 1,3-diols 5a and 5d were obtained by borane reduction of aldols 2a and 2d respectively.
Preparation of α,α-Bis(phenylseleno)ketones
Ponthieux, Sylvain,Outurquin, Francis,Paulmier, Claude
, p. 6453 - 6456 (2007/10/02)
α,α-Bis(phenylseleno)ketones have been synthesized by phenylselenenylation of enolates derived from α-phenylseleno ketones.Depending on the structure of the ketones, three experimental procedures were adopted.
