61849-18-1Relevant academic research and scientific papers
A new solid-phase reaction system utilizing a temperature-responsive catalyst: Oxidative cyclization with hydrogen peroxide
Hamamoto, Hiromi,Suzuki, Yachiyo,Takahashi, Hideyo,Ikegami, Shiro
, p. 2685 - 2689 (2008/09/20)
A switchable catalyst based on temperature change provides a novel solid-phase reaction system in water. An increase in catalyst affinity for organic substrates at higher temperature led to efficient activity driving the solid inner-phase reaction, and loss of affinity at lower temperature allowed easy separation of organic products upon completion of the reaction. Application of this catalyst intelligence to design a novel catalytic system brought about an efficient oxidative cyclization with hydrogen peroxide, a useful method of accessing oxygen heterocycles.
