61856-19-7Relevant academic research and scientific papers
Addition of α-polyhalides to olefins under mild reaction conditions, catalyzed by Mo(CO)6
Shvo, Youval,Green, Revital
, p. 77 - 83 (2007/10/03)
Mo(CO)6 was found to be an efficient pre-catalyst in the 1,2-addition reaction of α-polyhalides to various olefins. Significantly, the reaction was run under mild conditions, viz. refluxing acetonitrile, with satisfactory yields. Cr(CO)6/
Telechelic oligomers by halogen atom transfer radical addition
Bellesia, Franco,Forti, Luca,Gallini, Elena,Ghelfi, Franco,Libertini, Emanuela,Pagnoni, Ugo M.
, p. 7849 - 7856 (2007/10/03)
Monodispersed telechelic oligomers have been efficiently prepared by Fe0-FeCl3 promoted halogen atom transfer radical of functional telogens and taxogens.
ADDITION OF TETRACHLOROMETHANE TO 1,5-HEXADIENE
Kotora, Martin,Hajek, Milan
, p. 393 - 396 (2007/10/02)
The 2:1 adduct as the final product of the addition of tetrachloromethane to 1,5-hexadiene catalyzed by copper(I)-butylamine complex was obtained in high yield (96percent) under mild reaction conditions.Predominant 1:1 adduct formation was observed in the presence of a palladium catalyst or dibenzoyl peroxide initiator.
Ruthenium(II)- and Rhenium(III)-catalysed Addition of Tetrahalogenomethanes to Alkenes and 1,ω-Dienes. Stereoselective Formation of cis-1,2-Disubstituted Cyclopentanes from 1,6-Dienes
Grigg, Ronald,Devlin, John,Ramasubbu, Ashok,Scott, Ronald M.,Stevenson, Paul
, p. 1515 - 1520 (2007/10/02)
Acetonitrile(trichloro)bis(triphenylphosphine)rhenium(III) is found to act as an initiator for the addition of carbon tetrachloride and bromotrichloromethane to terminal alkenes an dienes.Moderate to good yields of mono- and bis-adducts are obtained. 1,6-
ORGANOALUMINUM-INDUCED ADDITION OF POLYHALOMETHANE TO OLEFINS
Maruoka, Keiji,Sano, Hiromi,Fukutani, Yoshimi,Yamamoto, Hisashi
, p. 1689 - 1692 (2007/10/02)
A mild procedure for the trimethylaluminum-induced addition of polyhalomethane to olefins has been described.
