61883-03-2Relevant academic research and scientific papers
Hydroperoxidations of Alkenes using Cobalt Picolinate Catalysts
Peralta-Neel, Zulema,Woerpel
supporting information, p. 5002 - 5006 (2021/06/30)
Hydroperoxides were synthesized in one step from various alkenes using Co(pic)2as the catalyst with molecular oxygen and tetramethyldisiloxane (TMDSO). The hydration product could be obtained using a modified catalyst, Co(3-mepic)2, with molecular oxygen and phenylsilane. Formation of hydroperoxides occurred through a rapid Co-O bond metathesis of a peroxycobalt compound with isopropanol.
