61883-33-8Relevant academic research and scientific papers
REACTIONS EN MILIEU HETEROGENE SOLIDE-LIQUIDE FAIBLEMENT HYDRATE: II - LA REACTION DE WITTIG DANS LES SYSTEMES CARBONATES ALCALINS/SOLVANT ORGANIQUE APROTIQUE
Bigot, Yves Le,Delmas, Michel,Gaset, Antoine
, p. 339 - 350 (1986)
The use of alkaline carbonates in a slighty hydrated solid-liquid aprotic organic media allowed the synthesis of alkenes from polyfunctionnal aldehydes or activated ketones with high yield in a Z preferential stereochemistry.The reaction mechanism proposed takes in account the specific use of water on the solvation of cationic species at the solid-liquid interface to explain the Z.E alkene ratio.
