Tetrahedron p. 339 - 350 (1986)
Update date:2022-08-04
Topics:
Bigot, Yves Le
Delmas, Michel
Gaset, Antoine
The use of alkaline carbonates in a slighty hydrated solid-liquid aprotic organic media allowed the synthesis of alkenes from polyfunctionnal aldehydes or activated ketones with high yield in a Z preferential stereochemistry.The reaction mechanism proposed takes in account the specific use of water on the solvation of cationic species at the solid-liquid interface to explain the Z.E alkene ratio.
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