61907-83-3Relevant academic research and scientific papers
N-heterocycles from chromium aminocarbenes
Déry, Martin,Assouvie, Kevin,Heinrich, Nora,Rajotte, Isabelle,Lefebvre, Louis-Philippe D.,Legault, Marc-André,Spino, Claude
supporting information, p. 1312 - 1315 (2015/03/14)
The initial [2 + 2]-cycloadduct between a chromium aminocarbene and a tethered alkene undergoes a β-hydrogen elimination very efficiently when triphenylphosphine is added as a ligand. The reaction gives cyclic enamines or homoenamines depending on the sub
Monoalkylation of Primary Aliphatic Amines via N-Alkyl-N-(alkylthiomethyl)ammonium Chlorides. Evidence for the Formation of Stable N-Methylenealkylamines
Barluenga, Jose,Bayon, Ana M.,Asensio, Gregorio
, p. 427 - 428 (2007/10/02)
Monomeric N-methylenealkylamines (3), formed from N-alkyl-N-(alkylthiomethyl)ammonium chlorides (5) are stable at -60 deg C and may be trapped with organometallic reagents to provide the N,N-dialkylamines (8).
