6196-71-0Relevant academic research and scientific papers
Rapid and Efficient Microwave-Assisted Hydrophosphinylation of Unactivated Alkenes with H -Phosphinic Acids without Added Metal or Radical Initiator
Troupa, Panagiota,Katsiouleri, Georgia,Vassiliou, Stamatia
supporting information, p. 2714 - 2719 (2015/11/27)
A microwave-assisted hydrophosphinylation of unactivated alkenes with phosphinic acid and its derivatives under metal-free and initiator-free conditions is reported. Such hydrophosphinylations are operationally simple, use aqueous hypophosphorus acid, H-phenylphosphinic acid, and H-alkylphosphinic acids, and seem to proceed by a radical mechanism. Good isolated yields were obtained using a reasonable excess of the appropriate reagent.
BLACK PIGMENT DISPERSION
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Page/Page column 24-25, (2010/08/08)
Described is a pigment dispersion which is useful for electrophoretic displays comprising α) a bis-oxodihydro-indolylene-benzodifuranone colourant of the Formula (I) wherein the substituents are defined as in claim 1, β) a specific polymeric dispersant, and γ) a solvent which is suitable for dispersions used in electrophoretic displays. Also described are novel colourants and dispersants.
SYNTHESIS OF ACYCLIC AND CYLIC DIALKYLPHOSPHINIC ACIDS FROM AMMONIUM HYPOPHOSPHITE
Kurdyumova, N. R.,Ragulin, V. V.,Tsvetkov, E. N.
, p. 380 - 383 (2007/10/02)
The possibilities of synthesizing dialkylphosphinic and cyclic phosphinic acids from ammonium hypophosphite, hexamethyldisilazane, and corresponding halogen derivatives have been studied.These acids can be prepared in low yield, but the simplicity of the process compensates for this disadvantage.
Magnetic concentration and polymorphism in di-n-octyl-, di-n-decyl-, and di-n-dodecylphosphinates of copper(II)
Haynes, John S.,Oliver, Katherine W.,Thompson, Robert C.
, p. 1111 - 1117 (2007/10/02)
Phosphinates of copper(II) of the type Cu(R2PO2)2 where R is n-octyl, n-decyl, and n-dodecyl have been synthesized and characterized by differential scanning calorimetry, vibrational and electronic spectroscopy, and variable temperature (300 to 4.2 K) magnetic susceptibility studies.Each of these compounds was obtained in distinct α and β structural forms.All materials appear to have the double phosphinate bridged extended chain structure and the magnetic data have been successfully analyzed according to the isotropic Heisenberg model for linear chains.The α forms exhibit antiferromagnetic behaviour with J values of -25, -29, and -29 cm-1 for the octyl, decyl, and dodecyl derivatives respectively.The β forms are ferromagnetic and have corresponding J values of 1.8, 2.1, and 2.3 cm-1 respectively.Magneto-structural correlations in these extended chain coordination polymers are discussed.
