6196-98-1Relevant academic research and scientific papers
A novel InCl3/SiO2-catalyzed hydroarylation of arenes with styrenes under solvent-free conditions
Sun, Gaojun,Sun, Huayin,Wang, Zhiyong,Zhou, Ming-Ming
experimental part, p. 1096 - 1100 (2009/04/04)
A novel InCl3/SiO2-catalyzed hydroarylation of various styrenes with arenes has been developed. The reaction can be carried out under solvent-free conditions to afford a series of 1,1-diarylalkanes in high yields and with good regioselectivities. The catalyst can be reused six times without obvious loss of catalytic activity. Georg Thieme Verlag Stuttgart.
THERMAL TRANSFER FLUID: 1-PHENYL-1-TETRAHYDRONAPHTHYLETHANE.
Matsumoto,Furukawa,Tanaka,Yano,Kamita
, p. 215 - 218 (2007/10/14)
Naphthalene was selectively hydrogenated to tetralin, followed by reaction with styrene to give 1-phenyl-1-tetrahydronaphthylethane in 87% yield. Efficient catalysts for the reaction were 90% sulfuric acid or solid acids possessing acid sites of H//0 less than or equal to minus 5. 6. Purified 1-phenyl-1-tetrahydronaphthylethane has favored properties for a high boiling point thermal transfer fluid: boiling point, 342 C; pour point minus 37. 5 C; good thermal stability, etc. On severe heating, it decomposed to low fractions to some extent with little tendency to polymerization.
