62021-34-5Relevant academic research and scientific papers
CARBON-CARBON BOND FORMATION BY ADDITION OF ?-RADICALS TO ALKENES
Giese, Bernd,Gomez, Juan Antonio Gonzalez
, p. 2765 - 2766 (1982)
Cyclopropylmercury bromide and 7-norbornylmercury bromide, respectively, react with NaBH4 and alkenes 2 via ?-radicals 6 and 7 to yield products 9 and 11 by carbon-carbon bond formation.
Selectivity of ?-Radicals
Giese, Bernd,Gonzalez-Gomez, Juan-Antonio
, p. 1291 - 1300 (2007/10/02)
The ?-radicals 1-3 can be generated by reduction of alkylmercuric salts 5-7 with NaBH4.Their reactions with electronpoor alkenes 8 lead to CC-bond formation products 9-11 (Table 1).Kinetic measurements show that ?-radicals are as selective as ?-radicals i
