62056-37-5

Upstream product

• 1586-92-1 diethyl(ethoxy)aluminum 
• 1184-58-3 dimethylaluminum chloride 
• 1147357-15-0 C₁₈H₂₀O 
• 87639-14-3 C₁₈H₁₈O₂ 
• 1669-55-2 1-(4-methylphenyl)-3-phenyl-1-propen-3-ol 
• 77134-00-0 3-(4-methylphenyl)prop-2-enyl acetate 
• 603-33-8 triphenylbismuthane 
• 22252-14-8 (E)-3-(4-methylphenyl)-1-phenyl-2-propen-1-one 
• 104-87-0 4-methyl-benzaldehyde 
• 34862-98-1 C₁₆H₁₅Br 
• 591-50-4 iodobenzene 
• 58824-48-9 1-(4-methylphenyl)-2-propen-1-ol 
• 5012-90-8 4-methylphenyl phenethyl ketone 
• 622-97-9 1-ethenyl-4-methylbenzene 

Downstream Products

• 102759-90-0 1-Phenyl-3-p-tolyl-3-(N,N'-dicarbethoxy-hydrazino)-1-propen 
• 102758-41-8 1-Phenyl-3-p-tolyl-3-(N,N'-dicarbethoxy-hydrazino)-propan 
• 79542-20-4 (E)-2-phenyl-3-(p-tolyl)acrylaldehyde 
• 1452128-85-6 (E)-3-phenyl-2-(p-tolyl)acrylaldehyde 
• 1631035-62-5 1-(1-fluoro-3-phenylpropyl)-4-methylbenzene 
• 134539-88-1 2-((E)-1-Phenyl-3-p-tolyl-allyl)-2-(2,2,2-trifluoro-1-trifluoromethyl-ethyl)-malononitrile 
• 134539-89-2 2-((E)-3-Phenyl-1-p-tolyl-allyl)-2-(2,2,2-trifluoro-1-trifluoromethyl-ethyl)-malononitrile 

Relevant academic research and scientific papers

Palladacycle-Catalyzed Regioselective Heck Reaction Using Diaryliodonium Triflates and Aryl Iodides

We describe a P-containing palladacycle-catalyzed regioselective Heck reaction of 2,3-dihydrofuran with diaryliodonium salts and aryl iodides to afford 2-aryl-2,5-dihydrofurans and 2-aryl-2,3-dihydrofurans, respectively, in good yields. Mechanistic studie

Nickel-Catalyzed Reductive Csp2-Csp3Cross Coupling Using Phosphonium Salts

A nickel-catalyzed reductive cross coupling with phosphonium salts and allylic C(sp3)-O bond electrophiles, which granted direct construction of the C(sp2)-C(sp3) bond, is successfully developed. The protocol features broad substrate scope, high-functional-group tolerance, and heterocycle compatibility. Notably, the much more challenging reductive cross coupling with heterocyclic thiazolylphosphonium salts has also been accomplished for the first time.

In Situ Ring-Closing Strategy for Direct Synthesis of N-Heterocyclic Carbene Nickel Complexes and Their Application in Coupling of Allylic Alcohols with Aryl Boronic Acids

A in situ ring-closing strategy was developed for the synthesis of N-heterocyclic carbene nickel complexes. The process was carried out in air, and did not require solvent purification. The resulting nickel complexes were investigated as catalysts for the coupling of allylic alcohols with aryl boronic acids. A wide range of allylic substrates and aryl acids proved to be applicable to this catalytic system. Control experiments suggest that the Ni(0) may be the true active species in the coupling reactions. (Figure presented.).

A photocatalyst-free photo-induced denitroalkylation of β-nitrostyrenes with 4-alkyl substituted Hantzsch esters at room temperature

A photocatalyst-free stereoselectively photo-induced strategy for the denitroalkylation of β-nitrostyrenes using 4-alkyl substituted Hantzsch esters as the alkyl source under xenon lamp irradiation is developed. The reaction proceeds at room temperature and affords the corresponding products in moderate to excellent yields. The oxidant di-t-butyl peroxide serves as an efficient radical initiator under irradiation of a Xenon lamp, initiating alkyl radicals from the 4-alkyl substituted Hantzsch esters.

C–C Cross-Coupling Reactions of Organosilanes with Terminal Alkenes and Allylic Acetates Using PdII Catalyst Supported on Starch Coated Magnetic Nanoparticles

Starch coated magnetic nanoparticles supported palladium catalyst has been explored to perform C–C cross coupling reactions, such as oxidative Heck coupling and Tsuji–Trost allylic coupling using organosilicon compounds as one of the coupling partners. The biopolymer coated magnetic catalyst was very easy to recover magnetically and was efficiently recycled in the subsequent batches. All the reactions were performed in air and thus the necessity of air and moisture free reaction condition is avoided. The present protocols show wide substrate scope and good yields of the products.

Pd/Cu-catalyzed facile approach to stilbenes: A novel diversity of TosMIC as an aryl source

Pd/Cu-catalyzed Heck type cross-coupling reaction of p-toluenesulfonylmethyl isocyanide (TosMIC) with various styrenes to access stilbenes in DMSO solvent under mild conditions is developed. This efficient and simple approach employs TosMIC as an aryl sou

[Pd]-Catalyzed Intermolecular Coupling and Acid Mediated Intramolecular Cyclodehydration: One-Pot Synthesis of Indenes

An efficient one-pot synthesis of indenes from simple starting materials is presented. This process involves a dual C–C bond formation through an intermolecular Heck coupling reaction followed by acid-mediated intramolecular cyclodehydration. The strategy

Direct Reduction of Allylic Alcohols Using Isopropanol as Reductant

The lithium cation-catalyzed direct reduction of allylic alcohols to alkenes using isopropanol as a hydride donor was developed. The hydride transfer of the in situ-generated lithium isopropoxide to an allylic cation is the key process in this transformation. The reaction generates only water and acetone as byproducts, which highlights the synthetic utility of this method. (Figure presented.).

Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst

Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol% of a Bedford-type palladacycle catalyst is described. The developed methodology is applicable for a wide range of cinnamyl acetates furnishing excellent yields of up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under an air atmosphere.

Iron-Catalyzed Grignard Cross-Couplings with Allylic Methyl Ethers or Allylic Trimethylsilyl Ethers

We have found that cross-coupling between aryl Grignard reagents and allylic methyl ethers proceeded well in the presence of a catalytic amounts of Fe(acac) 3 to afford the corresponding allylic substitution products in good yields. Under the same conditions, allylic trimethylsilyl ethers also reacted with Grignard reagents to give the corresponding cross-coupling products.