6208-91-9

Basic information

• Product Name: 2-Dodecenoic acid, methyl ester, (2E)-
• Synonyms: 2-Dodecenoic acid, methyl ester, (2E)-;METHYLDODEC-2-ENOATE;methyl (E)-2-dodecenoate
• CAS NO: 6208-91-9
• Molecular Formula: C₁₃H₂₄O₂
• Molecular Weight: 212.33
• Mol File: 6208-91-9.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Dodecenoic acid, methyl ester, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Dodecenoic acid, methyl ester, (2E)-(6208-91-9)
• EPA Substance Registry System: 2-Dodecenoic acid, methyl ester, (2E)-(6208-91-9)

Safety Data

• Hazardous Substances Data: 6208-91-9(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 32466-54-9 (E)-2-dodecenoic acid 
• 112-31-2 caprinaldehyde 
• 1067-74-9 Methyl diethylphosphonoacetate 
• 5927-18-4 trimethyl phosphonoacetate 
• 1529-78-8 [(methoxycarbonyl)methyl]triphenylarsonium bromide 
• 22104-72-9 methyl trans/cis-2-dodecanoate 
• 74-88-4 methyl iodide 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 248605-41-6 cyclo (Gly-L-Lys(Z)-L-Val-3(S)-aminododecanoyl-) 
• 172941-85-4 cyclo (Gly-L-Lys(Z)-L-Val-3(R)-aminododecanoyl-) 
• 172941-42-3 methyl 3N-benzylaminododecanoate 
• 22104-81-0 (2E)-dodec-2-en-1-ol 
• 55928-65-9 cis-2-dodecanoic acid 
• 32466-54-9 (E)-2-dodecenoic acid 

Relevant articles and documents

Oxoammonium-Mediated Allylsilane–Ether Coupling Reaction

A new C(sp3)?H functionalization reaction consisting of the oxidative α-allylation of allyl- and benzyl- methyl ethers has been developed. The C?C coupling could be carried out under mild conditions thanks to the use of cheap and green oxoammonium salts. The scope of the reaction was studied over 27 examples, considering the nature of the substituents on the two coupling partners.

DEOXYDEHYDRATION OF SUGAR DERIVATIVES

The disclosure provides methods for deoxydehydration of sugar-based derivatives using hydrogen gas as a reducing agent.

Cylindrocyclophane biosynthesis involves functionalization of an unactivated carbon center

The cylindrocyclophanes are a family of natural products that share a remarkable paracyclophane carbon scaffold. Using genome sequencing and bioinformatic analyses, we have discovered a biosynthetic gene cluster involved in the assembly of cylindrocyclophane F. Through a combination of in vitro enzyme characterization and feeding studies, we confirm the connection between this gene cluster and cylindrocyclophane production, elucidate the chemical events involved in initiating and terminating an unusual type I polyketide synthase assembly line, and discover that macrocycle assembly involves functionalization of an unactivated carbon center.