6209-56-9

Upstream product

• 696-63-9 4-Methoxybenzenethiol 
• 78-94-4 methyl vinyl ketone 

Downstream Products

• 124531-27-7 4-(4-methoxyphenylthio)-2-methyl-1-butenecarbonitrile 
• 98096-59-4 (E)-5-(4-Methoxy-phenylsulfanyl)-3-methyl-pent-2-enoic acid ethyl ester 
• 98096-59-4 ethyl 5-(4-methoxyphenylthio)-3-methyl-2-pentenoate 

Relevant academic research and scientific papers

Supported cobalt complex-catalysed conjugate addition of indoles, amines and thiols to α,β-unsaturated compounds

A highly active and reusable supported Co(ii) complex on SBA-15 shows an excellent activity and selectivity to target products in aza- and thia-Michael conjugate additions of indoles, amines and thiols to α,β-unsaturated compounds under solventless mild reaction conditions. The Co-catalyst was also highly reusable and comparably more active than related catalysts in the reaction.

Study of the Michael addition of β-cyclodextrin-thiol complexes to conjugated alkenes in water

An environmentally benign and highly efficient supramolecular Michael addition of thiols from the secondary side of β-cyclodextrin to α,β-unsaturated compounds at the primary side in water is described in quantitative yields; products of undesirable side

Conjugate addition of indoles and thiols with electron-deficient olefins catalyzed by Bi(OTf)3

Conjugate addition of indoles and thiols with a variety of electron-deficient olefins mediated by a catalytic amount of Bi(OTf)3 at ambient temperature to afford the corresponding Michael adducts in good to excellent yields with high selectivity is reported.