Cas 62126-58-3,Li(1+)*AlH(C6H5)3(1-)=LiAlH(C6H5)3

62126-58-3

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Basic information

Product Name: Li⁽¹⁺⁾*AlH(C₆H₅)3^(1-)=LiAlH(C₆H₅)3
Synonyms:
CAS NO:62126-58-3
Molecular Formula:
Molecular Weight: 266.248
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: Li⁽¹⁺⁾*AlH(C₆H₅)3^(1-)=LiAlH(C₆H₅)3(CAS DataBase Reference)
NIST Chemistry Reference: Li⁽¹⁺⁾*AlH(C₆H₅)3^(1-)=LiAlH(C₆H₅)3(62126-58-3)
EPA Substance Registry System: Li⁽¹⁺⁾*AlH(C₆H₅)3^(1-)=LiAlH(C₆H₅)3(62126-58-3)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 62126-58-3(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 62126-58-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,2,1,2 and 6 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 62126-58:
(7*6)+(6*2)+(5*1)+(4*2)+(3*6)+(2*5)+(1*8)=103
103 % 10 = 3
So 62126-58-3 is a valid CAS Registry Number.

62126-58-3Upstream product

62126-58-3Downstream Products

62126-58-3Relevant academic research and scientific papers

Redistribution Reactions Involving Lithium Aluminium Hydride and Lithium Tetraphenylaluminate

Ashby, E. C.,Goel, A. B.

, p. 134 - 138 (2007/10/02)

Redistribution reactions involving LiAlH4 and LiAlPh4 were performed by mixing the reagents in appropriate ratios.The products: LiAlH3Ph, LiAlH2Ph2 and LiAlHPh3 were isolated and characterised by elemental analysis, infrared and nmr spectroscopy and DTA-TGA analysis.These products were also prepared by the reaction of PhLi with AlHnPh3-n (where n=1-3) in diethylether.Also PhAlH2 and Ph2AlH were prepared by the reaction of Ph3Al and AlH3 in both diethyl ether and THF in the appropriate stoichiometric ratios.

Nature of alkyl-hydrogen exchange reactions involving aluminum and zinc. 5. Reactions of diphenylzinc with lithium aluminum hydride in diethyl ether and tetrahydrofuran. Preparation of PhZn2H3

Ashby,Goel

, p. 1096 - 1101 (2008/10/08)

The reactions of diphenylzinc with lithium aluminum hydride in diethyl ether and THF have been studied in detail. Although ZnH2 as an insoluble solid and LiAlPhnH4-n in solution are formed when the Ph2Zn:LiAlH4 ratio is 2:1, 3:2, 1:1, and 1:2 in ether, no ZnH2 is formed when Ph2Zn is allowed to react with LiAlH4 in THF in ratios varying from 4:1 to 1:2. Instead, PhZn2H3 is formed which is insoluble in THF. This compound is reported for the first time, and its existence is supported by IR, X-ray powder diffraction, and DTA-TGA studies. When ZnH2, prepared by the reaction of Ph2Zn with LiAlH4 in ether, was allowed to react with Ph2Zn and cyclopentadiene independently in THF, the insoluble products PhZn2H3 and CpZn2H3 formed. Reaction of cyclohexanol with ZnH2 is also discussed.

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