62127-41-7Relevant academic research and scientific papers
Preparation of first examples of RFCCIF4 molecules. A study of the fluorination of selected 1-iodoalk-1-ynes with xenon difluoride/boron trifluoride
Bardin, Vadim V.,Frohn, Hermann-Josef
, p. 98 - 104 (2013/04/10)
First examples of alk-1-yn-1-yliodine(V) molecules, CF3CCIF 4 and C6F13CCIF4, were prepared by fluorination of the corresponding 1-iodoperfluoroalk-1-ynes with XeF2 in 1,1,1,3,3-pentafluoro
Experimental and theoretical studies on the reactivities of partially and fully fluorinated primary alkyl radicals
Bartberger, Michael D.,Dolbier Jr., William R.,Lusztyk,Ingold
, p. 9857 - 9880 (2007/10/03)
Absolute rate constants for hydrogen abstraction from n-Bu3SnH by a number of partially-fluorinated and fully fluorinated n-alkyl radicals have been measured. The C-H and C-C bond dissociation energies for a number of pertinent hydrofluorocarbons have been calculated by DFT. The rate data are compared with those for addition of the same radicals to styrene, and the reactivities of these radicals are discussed in terms of their electronegativies, their structure and the thermodynamics of their reactions.
