6216-31-5

Upstream product

• 25494-23-9 (1,2-3,5)-1,2-Di-O-acetyl-3,5-diacetamido-cyclopentan-diol-(1,2) 
• 25583-05-5 (1,2-3,5)-3,5-Diacetylamido-cyclopentan-diol-(1,2) 
• 62708-23-0 Acetic acid (1R,2S,3S,4R,5R,6S)-2,3-diacetoxy-5-chloro-4,6-bis-(toluene-4-sulfonyloxy)-cyclohexyl ester 
• 3055-46-7 N-((4R,5S,6R)-4,5-Dihydroxy-6-hydroxymethyl-2-methoxy-tetrahydro-pyran-3-yl)-acetamide 
• 69892-50-8 N-((3R,4R,5S,6R)-4,5-Bis-benzyloxy-2-methoxy-6-trityloxymethyl-tetrahydro-pyran-3-yl)-acetamide 
• 81308-75-0 Acetic acid (1S,2S,3R,4R,5S,6S)-2-acetylamino-3,4-bis-benzyloxy-5-hydroxy-6-nitro-cyclohexyl ester 
• 81308-76-1 N-((1S,2R,3R,4S,5R)-2,3-Bis-benzyloxy-4-hydroxy-5-nitro-cyclohexyl)-acetamide 
• 69892-52-0 2-acetamido-3,4-di-O-benzyl-2-deoxy-D-glucopyranoside 
• 42756-57-0 methyl 2-acetamido-2-deoxy-6-O-trityl-D-glucopyranoside 
• 72-87-7 N-acetyl-D-glucosamine 
• 69940-08-5 N-((1S,2R,3R,4S,5R,6S)-2,3-Bis-benzyloxy-4,6-dihydroxy-5-nitro-cyclohexyl)-acetamide 
• 108-24-7 acetic anhydride 
• 62708-24-1 Acetic acid (1S,2S,3R,4R,6S)-2,3-diacetoxy-4,6-bis-(toluene-4-sulfonyloxy)-cyclohexyl ester 
• 137555-88-5 Trifluoro-methanesulfonate[(3aR,4S,5R,7S,7aR)-7-acetylamino-2,2-dimethyl-4-(tetrahydro-pyran-2-yloxy)-hexahydro-benzo[1,3]dioxol-5-yl]-[1-dimethylamino-meth-(E)-ylidene]-methyl-ammonium; 

Downstream Products

• 6216-32-6 1,3-Bis-N-(benzyloxycarbonyl)-2-desoxystreptamin 
• 2037-48-1 2-deoxystreptamine 

Relevant academic research and scientific papers

REDUCTIVE ONE-STEP ELIMINATION OF AN ACETOXYL RESIDUE AT β-POSITION OF A NITRO GROUP: SYNTHESES OF (-)-SHIKIMIC ACID FROM D-MANNOSE AND 2-DEOXYSTREPTAMINE PENTAACETATE FROM N-ACETYL-D-GLUCOSAMINE

By utilizing a reductive one-step elimination reaction of an acetoxyl residue at β-position of the nitro group in cyclitols, a synthesis of the ketocyclitol triacetate (15a), which was already converted to (-)-shikimic acid (16) and (-)-guinic acid (17), from D-mannose (4) and a conversion from N-acetyl-D-glucosamine (18) to 2-deoxystreptamine pentaacetate (22) have been accomplished.