62183-29-3

Basic information

• Product Name: Propanoic acid, 2,2-dimethyl-, 1-cyclohexen-1-yl ester
• CAS NO: 62183-29-3
• Molecular Formula: C11H18O2
• Molecular Weight: 182.263
• Mol File: 62183-29-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Propanoic acid, 2,2-dimethyl-, 1-cyclohexen-1-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanoic acid, 2,2-dimethyl-, 1-cyclohexen-1-yl ester(62183-29-3)
• EPA Substance Registry System: Propanoic acid, 2,2-dimethyl-, 1-cyclohexen-1-yl ester(62183-29-3)

Safety Data

• Hazardous Substances Data: 62183-29-3(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 1538-75-6 2,2-dimethylpropanoic anhydride 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 3282-30-2 pivaloyl chloride 

Downstream Products

• 1253579-26-8 2-(cyclohex-1-en-1-yl)-5,5-dimethyl-1,3,2-dioxaborinane 

Relevant articles and documents

Rhodium-catalyzed borylation of aryl and alkenyl pivalates through the cleavage of carbonoxygen bonds

Rhodium-catalyzed borylation reactions of aryl and alkenyl pivalates, using a diboron reagent, via the cleavage of carbonoxygen bonds have been developed. The inert nature of the pivalate moiety enables relatively complex aryl boronates to be synthesized via the tandem cross-coupling of carbonhalogen and carbonoxygen bonds.

Selective O-acylation of silyl enol ethers with acid halides mediated by a copper(I) salt

A new selective synthetic method of enol esters (O-acylated products) from silyl enol ether and acid chloride in the presence of CuCl is described. This reaction proceeds smoothly in DMI (1,3-dimethyl-2-imidazolidinone) but not in a less polar solvent. The silicon-copper exchange reaction pathway is proposed for this transformation as in the cases of D and alkynylsilane which were previously reported.