62199-59-1

Upstream product

• 598-25-4 Dimethylallene 
• 1079-66-9 chloro-diphenylphosphine 
• 598-23-2 3-methyl-but-1-yne 
• 603-35-0 triphenylphosphine 

Downstream Products

• 109976-10-5 1-(tert-Butylphenylphosphino)-1-(diphenylphosphino)-3-methyl-1,2-butadien 
• 940912-92-5 1,1-bis(diphenylphosphino)-2-(1-methylethyl)-3-methyl-1-butene 
• 116204-17-2 (3-methyl-1-butynyl)diphenylphosphine sulfide 
• 38117-54-3 cyclopentadienyl iron(II) dicarbonyl dimer 
• 62475-91-6 diiron(carbonyl)6(μ2-η2-CC(isopropyl))(μ-PPh2) 
• 110511-63-2 ruthenium3(carbonyl)10((phenyl)2P(i-Pr)C₂)2 
• 77700-85-7 ruthenium3(carbonyl)11{(phenyl)2PCC(i-Pr)} 
• 113552-02-6 HRu₃(CO)9(P(C₆H₅)2)(P(C₆H₅)2(C₂CH(CH₃)2)) 
• 115880-87-0 [(E)-3-methyl-1-butenyl]diphenylphosphine oxide 

Relevant academic research and scientific papers

Chromium catalysts for ethylene trimerization/tetramerization functionalized with ortho-fluorinated arylphosphine ligand

A series of novel asymmetric bidentate phosphines with ortho?fluorine substituents was developed and characterized. In combination with chromium, the compound gave high activity to 1-hexene and 1-octene (approaching 3200 kg/g Cr/h) and high combined selec

Copper-catalyzed anti-hydrophosphination reaction of 1-alkynylphosphines with diphenylphosphine providing (Z)-1,2-diphosphino-1-alkenes

Hydrophosphination of 1-alkynylphosphines with diphenylphosphine proceeds in an anti fashion under copper catalysis, providing an easy and efficient access to a variety of (Z)-1,2-diphosphino-1-alkenes and their sulfides. The reaction is highly chemoselec

Phosphine-substituted and phosphido-bridged metal clusters in homogeneous catalysis I. Synthesis and reactivity of (η5-C5H5)NiM3(μ-H)3(CO)(9-n)Ln (M = Ru, Os, n = 1,2: L = PPh3, PPh2H, PCy3, PEt3) and M3(CO)(12-n)Ln (M = Ru, N = 1-3: L = PPh3,

The complexes (η5-C5H5)NiM3(μ-H)3(CO)(9-n)Ln (M = Ru, Os, n = 1.2: L = PPh3, PPh2H, PCy3, PEt3) and M3(CO)(12-n)Ln (M = Ru, n = 1-3: L = PPh3, PPh2H, PCy3, PEt3; M = Os, n = 1,2: L = PPh3) have been synthesized by new or known procedures.Reacti

Syntheses and Structures of Simple Mono- and Bis(phosphino)allenes

Metalation of 1,1-dimethylallene with alkyllithium compounds and treatment of the resulting lithiated products with chlorodiphenylphosphane affords 3,3-dimethyl-1-(diphenylphosphino)allene and -1,1-bis(diphenylphosphino)allene (3 and 8, respectively).The success of the syntheses depends strongly on the reaction conditions.With a change in stoichiometry, temperature, or reaction times, isomeric alkynes (CH3)2CH-C*C-P(C6H5)2 and (C6H5)2P(CH3)2C-C*CH (6 and 7, respectively) are also obtained, and even substitution of phenyl for alkyl groups at the phosphorus atom may occur.Thus the reaction of the intermediate 6 with tert-butyllithium followed by treatment with (C6H5)2PCl leads to the allene (CH3)2C=C=C (12).Through the new preparative methods, mono- and (geminally) bis(phosphino)-substituted allenes have now become easily available in good yields.The prototypes 8 and 12 have been structurally characterized by X-ray diffraction analyses.The molecular conformations are very similar to those of analogous geminal di(phosphino)alkenes.