(3-Methylbut-1-yn-1-yl)(diphenyl)phosphane

Base Information

Chemical Name:(3-Methylbut-1-yn-1-yl)(diphenyl)phosphane
CAS No.:62199-59-1
Molecular Formula:C17H17P
Molecular Weight:252.296
Hs Code.:
DSSTox Substance ID:DTXSID10552686
Nikkaji Number:J2.446.492J
Wikidata:Q82433050

Synonyms:62199-59-1;(3-Methylbut-1-yn-1-yl)(diphenyl)phosphane;SCHEMBL22882963;DTXSID10552686

Suppliers and Price of (3-Methylbut-1-yn-1-yl)(diphenyl)phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3-Methylbut-1-yn-1-yl)(diphenyl)phosphane

Chemical Property:

XLogP3:4.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:252.106787540
Heavy Atom Count:18
Complexity:276

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)C#CP(C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of (3-Methylbut-1-yn-1-yl)(diphenyl)phosphane

There total 4 articles about (3-Methylbut-1-yn-1-yl)(diphenyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 598-23-2
3-methyl-but-1-yne

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 62199-59-1
(3-methyl-1-butynyl)diphenylphosphine

Guidance literature:: 3-methyl-but-1-yne; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.5h;

chloro-diphenylphosphine; In tetrahydrofuran; hexane; at 20 ℃; for 1h;
DOI:10.1021/ja070048d

Reference yield:

: 598-25-4
Dimethylallene

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 62199-59-1
(3-methyl-1-butynyl)diphenylphosphine

Guidance literature:: With n-butyllithium; Yield given. Multistep reaction; 1) ether, hexane, RT, 2 h, 2) ether, RT;

Reference yield:

: NiOs₃H₃⁽¹⁺⁾*C₅H₅^(1-)*8CO*P(CCCH(CH₃)2)(C₆H₅)2=(C₅H₅)NiOs₃H₃(CO)8P(C₂CH(CH₃)2)(C₆H₅)2

: 603-35-0
triphenylphosphine

: NiOs₃H₃⁽¹⁺⁾*C₅H₅^(1-)*8CO*P(C₆H₅)3=(C₅H₅)NiOs₃H₃(CO)8(P(C₆H₅)3)

: 62199-59-1
(3-methyl-1-butynyl)diphenylphosphine

Guidance literature:: In hexane; The complex and a slight excess of Pp is refluxed in hexane for 5 min (N2). 3% decompn.; The reaction soln. was filtered and concd. to small vol. under reduced pressure then subjected to preparative thin layer chromy. (silica gel; light petroleum/diethyl ether).;
DOI:10.1016/0022-328X(88)80047-0