62202-86-2Relevant articles and documents
New Syntheses with Magnesium Hydride. Part 1: Hydromagnesiation of α-Olefins to Magnesium-dialkyls
Knott, Wilfried,Klein, Klaus-Dieter
, p. 914 - 918 (2007/10/02)
The addition of highly active magnesium hydride to α-olefins, hydromagnesiation, is a well known reaction.The use of cheap magnesium hydride exhibiting a lower reactivity is highly desirable for industrial purposes.In a combination of chemical and mechanical activation the low reactivity of high temperature magnesium hydride could be overcome thereby making a broad variety of magnesium alkyls accessible. Key words: Magnesium alkyls; hydromagnesiation; magnesium hydride.