62205-46-3Relevant academic research and scientific papers
Formation and stability of oxocarbenium ions from glycosides
Denekamp, Chagit,Sandlers, Yana
, p. 1055 - 1063 (2005)
Structural, protecting group and leaving group effects in the formation of oxocarbenium intermediates were studied in the gas phase. It is found that significant stabilization of oxocarbenium cations is achieved by protecting groups that interact with the
Thio-arylglycosides with various aglycon para-substituents: A probe for studying chemical glycosylation reactions
Li, Xiaoning,Huang, Lijun,Hu, Xiche,Huang, Xuefei
experimental part, p. 117 - 127 (2009/04/08)
Three series of thioglycosyl donors differing only in their respective aglycon substituents within each series have been prepared as representatives of typical glycosyl donors. The relative anomeric reactivities of these donors were quantified under compe
