36874-86-9Relevant academic research and scientific papers
Small molecule glycoconjugates with anticancer activity
Pastuch-Gawo?ek, Gabriela,Musio?, Marta,Malarz, Katarzyna,Serda, Maciej,Czaplinska, Barbara,Musiol, Robert,Mrozek-Wilczkiewicz, Anna
supporting information, p. 130 - 144 (2017/11/03)
Glycoconjugates are combinations of sugar moieties with organic compounds. Due to their biological resemblance, such structures often have properties that are desirable for drugs. In this study we designed and synthesised several glycoconjugates from smal
Palladium-catalyzed cross-coupling reaction of thioglycosides with (hetero)aryl halides
Brachet, Etienne,Brion, Jean-Daniel,Messaoudi, Samir,Alami, Mouad
, p. 477 - 490 (2013/05/08)
α- and β-thioglycosides serve as effective nucleophiles for Buchwald-Hartwig cross-coupling reactions using functionalized (hetero)aryl halides. The functional group tolerance on the electrophilic partner is typically high, both benzyl and acetate protect
Thio-arylglycosides with various aglycon para-substituents: A probe for studying chemical glycosylation reactions
Li, Xiaoning,Huang, Lijun,Hu, Xiche,Huang, Xuefei
experimental part, p. 117 - 127 (2009/04/08)
Three series of thioglycosyl donors differing only in their respective aglycon substituents within each series have been prepared as representatives of typical glycosyl donors. The relative anomeric reactivities of these donors were quantified under compe
Formation and stability of oxocarbenium ions from glycosides
Denekamp, Chagit,Sandlers, Yana
, p. 1055 - 1063 (2007/10/03)
Structural, protecting group and leaving group effects in the formation of oxocarbenium intermediates were studied in the gas phase. It is found that significant stabilization of oxocarbenium cations is achieved by protecting groups that interact with the
