6221-04-1Relevant articles and documents
Catalytic asymmetric synthesis of Pt- and Pd-PCP pincer complexes bearing a para-N pyridinyl backbone
Yen Wong, Esther Hui,Jia, Yu-Xiang,Li, Yongxin,Pullarkat, Sumod A.,Leung, Pak-Hing
, p. 22 - 27 (2018/03/21)
A diastereoselective catalytic asymmetric hydrophosphination reaction was performed using a palladacycle catalyst to produce chiral PCP phosphine ligand with high dr (95:5) and excellent enantioselectivity (>99% ee). Subsequent facile metalation of the ch
A general method for coupling unprotected peptides to bromoacetamido porphyrin templates
Choma, Christin T.,Kaestle, Karen,Akerfeldt, Karin S.,Kim, Ronald M.,Groves, John T.,DeGrado, William F.
, p. 6191 - 6194 (2007/10/02)
An N-terminal cysteine is used to displace bromide from a bromoacetylated porphyrin to yield a thioether linkage between the peptide and the template. Unlike amide coupling reactions, this approach should be compatible with any peptide sequence provided there is only a single cysteine.
