62217-35-0Relevant academic research and scientific papers
Synthesis of new functionalized compounds related to π-extended tetrathiafulvalenes with quinonoidal structures bearing a ferrocene moiety
Sarhan, Abd El-Wareth A. O.,Murakami, Makoto,Izumi, Taeko
, p. 1055 - 1066 (2002)
A number of π-extended conjugated tetrathiafulvalene (TTF) analogues were synthesized as new π-donors, and their structures and physical properties were determined. UV/Vis spectra and cyclic voltammetry of the π-extended ferrocenyl donors were studied in comparison with ferrocene, ferrocenylquinone, and the parent donor. A three-electron redox behaviour was observed. The absorption spectrum of the new donor 16 showed a slight red-shift and a slight increase in intensity relative to the compared compounds.
Synthesis and electrochemical studies of ferrocene-dithiafulvalenes (Fc-DTF) and 1,1′-bis(dithiafulvalenyl)ferrocene (DTF-Fc-DTF). An approach towards new conducting organic materials
Sarhan, Abd El-Wareth,Nouchi, Yoshiyuki,Izumi, Taeko
, p. 6353 - 6362 (2007/10/03)
Novel π-conjugated donor compounds based on the strong electron-donating ferrocene moiety and dithiafulvalene donors exhibited increased electron donor ability. The ferrocenylketones 4a,b, 5, 8 and 9 were synthesized via described methods, and allowed to react with 2-dimethoxyphosphinyl-1,3-benzodithiole (13) in the presence of n-BuLi at -78°C in dry THF to afford the corresponding ferrocene-dithiafulvalenes 14a,b, 18, 19 and 1,1′-bis(benzo-1,3-dithiol-2-ylidene)ethyl]ferrocene (15). Electrochemical properties of these new donor compounds were studied using cyclic voltammetry (CV) and UV-Vis spectra. CV and absorption spectra of the new compounds were studied in comparison with ferrocene (6) and dibenzo-tetrathiafulvalene DB-TTF 3. Two-electron and three-electron redox behaviors were observed as two waves. The absorption spectra showed a red-shift with a slight increase in the absorption intensities.
Synthesis and photochromic behaviour of new dipyrrolylperfluorocyclopentenes
Heynderickx, Arnault,Kaou, Ali Mohamed,Moustrou, Corinne,Samat, Andre,Guglielmetti, Robert
, p. 1425 - 1432 (2007/10/03)
The synthesis of new photoswitchable dipyrrolylethenes having different π-conjugated chain lengths, employing Wittig-Horner reaction, Knoevenagel condensation, Suzuki palladium catalyzed cross-coupling or Sonogashira coupling, is reported. Their photochemical behaviour, and in particular, their thermal stability has been investigated upon continuous irradiation with light of appropriate wavelengths.
