62218-01-3Relevant academic research and scientific papers
The Amine Catalysed Cleavage of Oligochloropolysilanes with HCl
Raml, Walter,Hengge, Edwin
, p. 29 - 36 (2007/10/02)
Tetrakis(trichlorosilyl)silan (neo-Si3Cl12) is cleaved in an amine catalysed reaction by HCl in benzene solution to tris(trichlorosilyl)silan HSi(SiCl3)3 (1).The amine catalysed cleavage of 1 with different amines and solvents is investigated.A new method for preparation of pentachlorodisilane HSi2Cl5 is described and a reaction mechanism for the cleavage is postulated. - Keywords: Oligochlorosilanes; SiSi-Cleavage with HCl; neo-Dodecachloropentasilane; Tris(trichlorosilyl)silane
