62222-26-8

Basic information

• Product Name: (4aR,6S,7R,8aS)-6-Methoxy-7-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol
• Synonyms: (4aR,6S,7R,8aS)-6-Methoxy-7-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol
• CAS NO: 62222-26-8
• Molecular Weight: 280.321
• Mol File: 62222-26-8.mol

Chemical Properties

• CAS DataBase Reference: (4aR,6S,7R,8aS)-6-Methoxy-7-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (4aR,6S,7R,8aS)-6-Methoxy-7-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol(62222-26-8)
• EPA Substance Registry System: (4aR,6S,7R,8aS)-6-Methoxy-7-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol(62222-26-8)

Safety Data

• Hazardous Substances Data: 62222-26-8(Hazardous Substances Data)

Upstream product

• 95058-48-3 (1aS,2S,6R,7bS)-2-Methoxy-1a-methyl-6-phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene 
• 95058-48-3 (1aR,2S,6R,7bR)-2-Methoxy-1a-methyl-6-phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene 
• 917-64-6 methyl magnesium iodide 
• 19272-50-5 Methyl-4,6-O-benzyliden-3-deoxy-α-D-erythro-hexo-pyranosid-2-ulose 
• 917-54-4 methyllithium 

Downstream Products

• 62222-30-4 methyl 2-O-benzyl-2-C-methyl-α-D-ribo-hexopyranoside 
• 62222-28-0 methyl 2-O-benzyl-4,6-O-benzylidene-2-deoxy-3-C-methyl-α-D-ribo-hexopyranoside 

Relevant articles and documents

Synthetic Routes to 6,8-Dioxabicyclooctyl Pheromones from D-Glucose Derivatives. 3. Synthesis of (-)-Frontalin

3-Deoxy-2-oxo glycosides with and without a C4 hydroxyl group are readily prepared from methyl α-D-glucopyranoside.Reaction with methylmagnesium iodide gives the C2 tertiary alcohol with an axially oriented methyl group.The epimeric tertiary alcohol can b